Emulsion polymerization of an epoxy-acrylate emulsion stabilized with polyacrylate. II. Using the results of statistically designed experiments to deduce a possible polymerization mechanism

2000 ◽  
Vol 76 (3) ◽  
pp. 368-381 ◽  
Author(s):  
D. De Wet-Roos ◽  
J. H. Knoetze ◽  
B. Cooray ◽  
R. D. Sanderson
Keyword(s):  
Emulsion Polymerization ◽  
Epoxy Acrylate ◽  
Polymerization Mechanism ◽  
Designed Experiments ◽  
Acrylate Emulsion

Study on Formulation for Epoxy Acrylic Hybrid Emulsion

2012 ◽  
Vol 524-527 ◽  
pp. 1715-1718
Author(s):  
Wen Lu Guo ◽  
Zhi Ming Jin ◽  
Cai Hua Gao
Keyword(s):  
Epoxy Resin ◽  
Emulsion Polymerization ◽  
Orthogonal Experiment ◽  
Epoxy Group ◽  
Epoxy Acrylate ◽  
Functional Monomer ◽  
Graft Polymer ◽  
Acrylate Emulsion ◽  
Ft Ir ◽  
Simple Technology

The epoxy acrylate emulsion was made by hybrid emulsion polymerization. This method has simple technology, none solvent and friend to the environment. The epoxy acrylate hybrid emulsion was prepared by using core-shell emulsion polymerization technology. The factors, such as epoxy resin, emulsifier ,initiator and functional monomer, were investigated by the orthogonal experiment. The relation of interactional factors was confirmed, and one kind of steady emulsion was made. The best formulation condition of modified emulsion could be obtained when N-MA was 1%, MAA was 2%, emulsifier was 3%, epoxy resin was 6%, initiator was 0.6%. The structure of modified styrene acrylic hybrid emulsion was characterized by FT-IR, the peaks at 915cm-1 and 1251cm-1 correspond respectively to the motion of epoxy group and phenylate, so the graft polymer was confirmed.

The preparation of a three-layer “core–shell” structured epoxy-acrylate emulsion

RSC Advances ◽  
2014 ◽  
Vol 4 (88) ◽  
pp. 47184-47190 ◽  
Author(s):  
Lizhu Liu ◽  
Jinfeng Li ◽  
Xiaorui Zhang ◽  
Ke Jin
Keyword(s):  
Core Shell ◽  
Epoxy Acrylate ◽  
Acrylate Emulsion

Preparation of epoxy acrylate emulsion using mixed surfactants and its polymerization

1996 ◽  
Vol 36 (2) ◽  
pp. 141-148 ◽  
Author(s):  
Jin-Woong Kim ◽  
Ju-Young Kim ◽  
Kyung-Do Suh
Keyword(s):  
Mixed Surfactants ◽  
Epoxy Acrylate ◽  
Acrylate Emulsion

A New Living Emulsion Polymerization Mechanism:  Episulfide Anionic Polymerization

2002 ◽  
Vol 35 (23) ◽  
pp. 8688-8693 ◽  
Author(s):  
A. Rehor ◽  
N. Tirelli ◽  
J. A. Hubbell
Keyword(s):  
Emulsion Polymerization ◽  
Anionic Polymerization ◽  
Polymerization Mechanism

scholarly journals Emulsion Polymerization of Chloroprene. Polymerization Mechanism and Evaluation of Crosslinking Density

1991 ◽  
Vol 23 (7) ◽  
pp. 859-864 ◽  
Author(s):  
Kenji Itoyama ◽  
Nobuhiro Hirashima ◽  
Junji Hirano ◽  
Takashi Kadowaki
Keyword(s):  
Emulsion Polymerization ◽  
Crosslinking Density ◽  
Polymerization Mechanism

Incorporation of Nonionic Emulsifiers Inside Particles in Emulsion Polymerization:  Mechanism and Methods of Suppression†

Langmuir ◽  
2006 ◽  
Vol 22 (21) ◽  
pp. 8727-8731 ◽  
Author(s):  
Masayoshi Okubo ◽  
Hiroshi Kobayashi ◽  
Takumi Matoba ◽  
Yoshiteru Oshima
Keyword(s):  
Emulsion Polymerization ◽  
Polymerization Mechanism
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